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The reasons for the breaking up of the sludge by the manufacturer of the broken emulsion
2015-10-22
The reasons for the breaking up of the sludge by the manufacturer of the broken emulsion
Source: http://www.cngzet.com release date: 2015-10-20
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Introduction
In the process of treating wastewater by activated sludge process, there are many reasons that can lead to the inhibition of the activity of activated sludge, which result in the change of the nature of microorganism and the removal rate of organic substrate. Excess growth of some microorganisms can form foam or scum, runtime mechanical stress force, coerced bubble will reduce float float away the proportion of activated sludge, which not only increased the effluent suspended solids, and reduce the activity and quantity of activated sludge in bioreactor systems. On the basis of reading a large number of domestic and foreign literature, the reasons for the inhibition of the activity of activated sludge and the reasons for the rise, the method and the control technology are discussed in this paper.
One, the main factors that cause the activated sludge floating:
1, water quality
(1) surfactant and excess grease compounds
This type of material can affect the stability and permeability of the cell membrane, so that some of the essential components of the cell loss and lead to microbial growth arrest and death. When the aeration tank in the water with a great deal of this kind of material, will produce a large number of foam, these bubbles easily agglomeration in zoogloea, the proportion of activated sludge reduce float. In addition, when in water containing oil is too high, after aeration and mixing, the oil will agglomeration in zoogloea surface, hypoxic cell death, resulted in decrease of specific gravity and buoyancy.
(2) PH shocks
Too high or too low pH will affect the activated sludge microbial extracellular enzymes and exist in cytoplasm and cell wall enzyme catalysis, and microorganisms on nutrient absorption. When the continuous flow aeration tank in pH < 4.0 or pH > 11.0, in most cases in activated sludge microbial activity inhibited, or loss of activity, and even death, so that the floating sludge.
(3) the effect of salt content
The influence of alkalinity on the activated sludge can not be eliminated by the adjustment of PH. The alkaline water PH, although neutralizing the alkaline substances, but produced a salt. The osmotic pressure of salt solution is also different, and osmotic pressure is one of the important factors that affect the survival of microorganisms. If the solution of the microorganism is in a sudden change, it will lead to the death of microbial cells.
(4) water temperature
The microorganism suitable for the active sludge is suitable for the temperature range of 15 to 35, and more than 45 of the activated sludge can cause most of the microorganisms in the activated sludge to float up (except for a long period of domestication or special microorganisms). In addition, the SBR process determination of temperature effects on intracellular enzyme activity test also found that temperature in 20, 30, 40 DEG C, the enzyme activity of better than 50 DEG C, enzyme activity decreased significantly.
(5) the toxic substrate
The substrates of the aerobic activated sludge microorganism are mainly including: high content of COD, organic compounds (phenol and its derivatives, alcohols, aldehydes and some organic acids), sulfides, heavy metals, etc..
High substrate concentrations can form stable compounds in the center of cell enzyme activities, which can not be close to the substrate, and can not be degraded, and even cause cell death.
After entering the cell, the heavy metal ions are mainly associated with the -SH binding to the enzyme or protein, which causes the inactivation or denaturation. Trace amounts of heavy metal ions can also accumulate in the cell eventually to the toxic effects of microorganisms (micro action).
The most common halide is iodine and chlorine, iodine is not reversible with the bacterial protein (or) the enzyme tyrosine to generate two iodine tyrosine, so that the bacteria inactivation. Chlorine and hydration of hypochlorite, the decomposition of strong oxidizing agent. And the organic matter in the waste water, the manufacturer of the organic matter of the broken emulsion can be tamed and can degrade the organic poison.
2, process operation
(1) excessive aeration
Microorganisms in the starvation state caused by their oxidation into the aging period, the pool of DO rise; or due to poor sludge activity, aeration impeller line speed is too high, oxygen too much, in short, DO rise, the short term sludge activity is good, because the fast metabolism, organic matter decomposition is fast, but time a long time, the sludge was beaten and light and broken (but no air bubbles), like the fog covered with the flow of the surface, with the flow of water. This kind of sludge color is light, the activity difference, the oxygen consumption rate is decreased, the sludge volume and the sludge index increase, the treatment effect is obviously decreased.
(2) the rise of sludge caused by hypoxia
The sludge is gray, and if the oxygen is too long, it is black and often with small bubbles.
(3) the rise of sludge caused by denitrification
When the content of organic ammonia in wastewater is high or ammonia nitrogen is high, it can be oxidized to NO3- by nitrate and nitrite under suitable conditions, such as the two sedimentation tank or the residence time is too long, the NO3- generated by N2 reduction can be activated by activated sludge, which makes the activated sludge float up.
(4) the return flow is too large to cause the sludge to float.
Back to the sudden flow rate increase will make gas and water separation is not complete, the bubbles in the aeration tank to the floating region precipitation, the sludge is granular, the same color, turned direction is from the wall of the diversion area straight to the settling zone wall into turbulent flip.
(5) two sludge floating in the bottom of the sink
If the two sink the pond sediment produced by fermentation, CO2 and H2 also agglomerated in activated sludge, the sludge reduced the proportion of floating. Sludge produced by the decay of H2S, CH4 after the surface, the first is a small bubble escape surface, followed by a black sludge floating.
2, the excessive growth of activated sludge filamentous bacteria and the control of sludge floating
(1) temperature and load
The optimal growth conditions of the strains were 12----15, and the sludge was negative.
(1) temperature and load
The optimal growth conditions of the strains were 12----15, and the sludge load was less than 0.1. Its natural hydrophobic can cause the dehydration of activated sludge, the highest for 490ml/g, the temperature is higher than 20, even if the sludge load is 0.2, the. It into pieces, into a form of floating scum.
(2) surfactant, lipids and mechanical stress
The most frequent filamentous bacteria caused by low load expansion and sludge floatation are the 0041 types of the actin filaments. In water surfactant and lipid compounds concentration increased, inoculation and mechanical stress can also cause the growth of actinomycetes. Mechanical stress (such as centrifugal pump) will damage the activated sludge and lead to excessive growth of the actin filament.
(3) an excess of a filamentous bacterium
In aeration tank, the H2S was decreased from 580 to 178, and hydrogen peroxide was also ensured by SVI and DO, and the effect of hydrogen peroxide on the aeration tank was ensured.
Two, the detection method of activated sludge inhibition and floating
1, the determination of the oxygen consumption rate of sludge (OUR) and ATP (ATP)
2, the use of biological diagnosis of activated sludge state and performance
Three, control of the technical measures of sludge floating
(1) the most feasible and economical method for stabilizing the water quality of the aeration tank is the water return, which is used to dilute and adjust the organic concentration in the influent of aeration tank, so as to make it stable in a certain range.
(2) the sewage treatment plant shall be considered to have a large pool and control good level, because the high level will make the buffer capacity of the adjustment pool, and even lost; and the low level is not homogeneous effect, and easy to make the oil and the bottom of the impurities into the aeration tank, the impact of activated sludge and floating. Liquid level should be controlled in 50---70%.
(3) reasonable investment and nutrition
Due to the imbalance of the proportion of the industrial wastewater, carbon sources are often sufficient and N, P is insufficient, so the treatment of industrial wastewater with additional compensation. Generally used urea and phosphate, but not too much.
(4) the inlet of the aeration tank is provided with a neutralization tank, and the PH automatic adjusting system.
(5) using pure oxygen aeration. Since West Germany imported pure oxygen aeration device in operation for 5 years has never been floating sludge.
(6) sludge caused by sludge can increase the amount of aeration, reduce water, remove dead mud.
(7) the microbial composition of the activated sludge is mainly dependent on the composition of the waste water, the flow pattern and the appropriate design. Because of the fact that it is difficult to control the composition of wastewater in the process, it is very important for the manufacturer to optimize the operation conditions and the design of the reactor.